Progresses of Damage and Protection for Surfaces and Interfaces in Machinery under Extreme Operating Conditions

Abstract

Abstract: The characteristics of extreme environments in the major projects were analyzed, the status and trend of surface and interface science in machinery at home and abroad were briefly reviewed, and the common scientific questions thereof were raised. Addressing the major strategic needs of the nation and the frontiers of international science, the research and development directions of surface and interface science in machinery under extreme operating conditions were proposed. Also, taking the study of protective coatings as an example of the key directions, the trends were discussed and the progresses of coating materials and technology were also reviewed.

Key words: extreme operating condition； surface and interface science in machinery； damage and protection, coating material and technology

摘要：

中国科学院宁波材料技术与工程研究所海洋新材料与应用技术重点实验室，宁波，315201
分析了重大工程实施中极端环境的典型特点，简要介绍了机械表面界面科学的国内外研究现状与发展趋势，指出了相关研究的共性科学问题；针对国家重大战略需求和国际研究前沿，提出了极端工况下机械表面界面科学领域的研究发展方向；以重点方向——功能防护涂层研究为例，探讨了涂层材料与技术的发展趋势并评述了相关研究进展。

关键词: 极端工况, 机械表面界面科学, 损伤与防护, 涂层材料与技术

CLC Number:

TH117

CHANG Keke, WANG Liping, XUE Qunji. Progresses of Damage and Protection for Surfaces and Interfaces in Machinery under Extreme Operating Conditions[J]. China Mechanical Engineering.

常可可, 王立平, 薛群基. [学科发展]极端工况下机械表面界面损伤与防护研究进展[J]. 中国机械工程.

References

[1]刘维民, 薛群基. 摩擦学研究及发展趋势[J]. 中国机械工程, 2000,11(1/2):76-80.
LIU Weimin, XUE Qunji. Research and Development of Tribology [J]. China Mechanical Engineering, 2000,11(1/2):76-80.
[2]雒建斌, 李津津. 摩擦学的进展和未来[J]. 润滑与密封, 2010,35(12):1-12.

LUO Jianbin, LI Jinjin.Advancements and Future of Tribology[J]. Lubrication Engineering, 2010,35(12):1-12.

[3]温诗铸. 材料磨损研究的进展与思考[J]. 摩擦学学报, 2008，28(1):3-7.

WEN Shizhu. Research Progress on Wear of Materials[J]. Tribology,2008，28(1):3-7.

[4]吴进怡, 肖伟龙, 杨雨辉, 等. 25钢在热带海洋环境下海水中的微生物腐蚀及其对力学性能的影响[J]. 中国腐蚀与防护学报, 2010, 30(5):359-363.

WU Jinyi, XIAO Weilong, YANG Yuhui, et al. Effect of Microbe on the Corrosion Behaviors and Mechanical Properties of 25 Carbon Steel in Tropical Seawater Condition[J]. Journal of Chinese Society for Corrosion and Protection, 2010, 30(5):359-363.

[5]丁康康, 范林, 郭为民, 等. 典型金属材料深海腐蚀行为规律与研究热点探讨[J]. 装备环境工程, 2019, 16(1):117-123.

DING Kangkang, FAN Lin, GUO Weimin.Deep Sea Corrosion Behavior of Typical Metal Materials and Research Hotspot Discussion[J]. Equipment Environmental Engineering, 2019, 16(1):117-123.

[6]王勋龙, 于青, 刘二虎, 等. 极地条件下船舶装备与材料检测现状及发展趋势[J]. 中国计量, 2018, 273(8):81-82.

WANG Xunlong, YU Qing, LIU Erhu, et al. Status and Development Trend of Ship Equipment and Material Inspection under Polar Condition[J]. China Metrology, 2018, 273(8):81-82.

[7]韩恩厚, 王俭秋, 吴欣强, 等. 核电高温高压水中不锈钢和镍基合金的腐蚀机制[J]. 金属学报, 2010,46(11):105-116.

HAN Enhou, WANG Jianqiu, WU Xinqiang, et al. Corrosion Mechanisms of Stainless Steel and Nickel Base Alloys in High Temperature High Pressure Water[J]. Acta Metallurgica Sinica, 2010,46(11):105-116.

[8]高立本, 沈健. 高温气冷堆的发展与前景[J]. 中国核工业, 2016（10）: 24-26.

GAO Liben, SHEN Jian.The Development and Perspective of HTGR[J]. China Nuclear Industry, 2016（10）: 24-26.

[9]STACHOWIAK G W. How Tribology Has Been Helping Us to Advance and to Survive[J]. Friction, 2017,5(3):233-247.

[10]姚志雄, 黄立峰, 黄健. 影响空间液体润滑的环境因素[J]. 润滑与密封, 2005（3）:159-161.

YAO Zhixiong, HUANG Lifeng, HUANG Jian. The Environmental Factors to Affect the Performance of Lubrication for Space Application[J]. Lubrication Engineering,2005（3）:159-161.

[11]张玉花, 肖杰, 张晓伟, 等. 嫦娥三号巡视器移动设计与实现[J]. 中国科学:技术科学, 2014,44(5):55-63.

ZHANG Yuhua, XIAO Jie, ZHANG Xiaowei, et al.Design and Implementation of ChangE-3 Rover Location System[J]. Scientia Sinica（Technologica）, 2014,44(5):55-63.

[12]赵德孜. 海洋环境下燃气轮机涡轮叶片的热腐蚀与防护[J]. 装备环境工程, 2011,8(5):106-109.

ZHAO Dezi.Hot Corrosion and Protection of Gas Turbine Blade in Marine Environment[J]. Equipment Environmental Engineering, 2011,8(5):106-109.

[13]陈力捷. 煤矿机械磨损失效分析和抗磨措施[J]. 煤炭技术, 2011(6):28-29.

CHEN Lijie.Failure Analysis of Abrasion of Coal Mine Machinery and Measures for Anti-abrasion[J]. Coal Technology, 2011(6):28-29.

[14]段艳军, 张颖. 复杂艰险山区高速铁路限制坡度的选择[J]. 山西建筑, 2019, 45(1):133-136.

DUAN Yanjun, ZHANG Ying.Selection of Restricted Slopes for High Speed Railways in Complex and Dangerous Mountainous Areas [J]. Shanxi Architecture, 2019, 45(1):133-136.

[15]SPALVINS T. A Review of Recent Advances in Solid Film Lubrication[J]. Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, 1987, 5(2):212.

[16]ROBERTS E W. Thin Solid Lubricant Films in Space[J]. Tribology International, 1990, 23(2):95-104.

[17]WANG Yanjun, LIU Zuomin. Tribological Properties of High Temperature Self-lubrication Metal Ceramics with an Interpenetrating Network[J]. Wear, 2008,265(11/12):1720-1726.

[18]LUO J K, FLEWITT A J, SPEARING S M, et al. Youngs Modulus of Electroplated Ni Thin Film for MEMS Applications[J]. Materials Letters, 2004,58(17/18): 2306-2309.

[19]ZALAR A , HOFMANN S. Depth Resolution of Multilayer Cr/Ni Thin Film Structures Deposited on Substrates with Different Roughness[J]. Vacuum, 1987, 37(1/2):169-173.

[20]THOMAS S, AL-HARTHI S H, SAKTHIKUMAR D, et al. Microstructure and Random Magnetic Anisotropy in Fe-Ni Based Nanocrystalline Thin Films[J]. Journal of Physics D: Applied Physics, 2008, 41(15):155009.

[21]GONG Fubao, SHEN Jun, GAO Runhua, et al. Influence of Heat Treatment on Microstructure and Mechanical Properties of FeCrNi Coating Produced by Laser Cladding[J]. Transactions of Nonferrous Metals Society of China, 2016,26:2117-2125.

[22]VAZ F, FERREIRA J, RIBEIRO E, et al. Influence of Nitrogen Content on the Structural, Mechanical and Electrical Properties of TiN Thin Films[J]. Surface & Coatings Technology, 2005, 191(2/3):317-323.

[23]BULL S J, BHAT D G, STAIA M H. Properties and Performance of Commercial TiCN Coatings. Part 2: Tribological Performance[J]. Surface & Coatings Technology, 2003, 163/164:507-514.

[24]IMANISHI N, KANAMURA K, TAKEHARA Z I. Synthesis of MoS2 Thin Film by Chemical Vapor Deposition Method and Discharge Characteristics as a Cathode of the Lithium Secondary Battery[J]. Journal of the Electrochemical Society, 1992,139(8):2082-2087.

[25]DING Qi, WANG Liping, WANG Yongxin, et al. Improved Tribological Behavior of DLC Films under Water Lubrication by Surface Texturing[J]. Tribology Letters, 2010,41(2):439-449.

[26]PIERLOT C, PAWLOWSKI L, BIGAN M, et al. Design of Experiments in Thermal Spraying: a Review[J]. Surface and Coatings Technology, 2008, 202(18): 4483-4490.

[27]ONICIU L M L, MURESAN L. Some Fundamental Aspects of Levelling and Brightening in Metal Electrodeposition[J]. Journal of Applied Electrochemistry, 1991, 21(7):565-574.

[28]CONRAD J R. Plasma Source Ion-implantation Technique for Surface Modification of Materials[J]. Journal of Applied Physics 1987, 62(11):4591-4596.

[29]PEI Y T, HOSSON J T M D. Functionally Graded Materials Produced by Laser Cladding[J]. Acta Materialia, 2000, 48(10):2617-2624.

[30]KIM M S, RYU J J, SUNG Y M. One-step Approach for Nano-crystalline Hydroxyapatite Coating on Titanium via Micro-arc Oxidation[J]. Electrochemistry Communications, 2007, 9(8):1886-1891.

[31]MEYERSON B S. Low-temperature Silicon Epitaxy by Ultrahigh Vacuum/Chemical Vapor Deposition[J]. Applied Physics Letters, 1986, 48(12):797-799.

[32]MITSUO A, UCHIDA S, AIZAWA T. Effect of Pulse Bias Voltage and Nitrogen Pressure on Nitrogen Distribution in Steel Substrate by Plasma Immersion Ion Implantation of Nitrogen[J]. Surface & Coatings Technology, 2004, 186(1/2):196-199.

[33]DING Qingqing, ZHANG Yin, CHEN Xiao, et al. Tuning Element Distribution, Structure and Properties by Composition in High-entropy Alloys[J]. Nature, 2019,574:223-227.

[34]YOUSSEF K M, ZADDACH A J, NIU C, et al. A Novel Low-density, High-hardness, High-entropy Alloy with Close-packed Single-phase Nanocrystalline Structures[J]. Materials Research Letters, 2015, 3(2): 95-99.

[35]CHOU Y L, YEH J W, SHIH H C . The Effect of Molybdenum on the Corrosion Behaviour of the High-entropy Alloys Co1.5CrFeNi1.5Ti0.5Mox in Aqueous Environments[J]. Corrosion Science, 2010, 52(8):2571-2581.

[36]ZHANG Hui, PAN Ye, HE Yizhu. Synthesis and Characterization of FeCoNiCrCu High-entropy Alloy Coating by Laser Cladding[J]. Materials & Design, 2011,32(4):1910-1915.

[37]CAI Yangchuan, MANLADAN S M, LUO Zhen. Tribological Behaviour of the Double FeCoNiCrCux Middle-entropy Alloy Coatings[J]. Surface Engineering 2019,35(1):14-21.

[38]HSU C Y, SHEU T S, YEH J W, et al. Effect of Iron Content on Wear Behavior of AlCoCrFexMo0.5Ni High-entropy Alloys[J]. Wear, 2010,268(5/6):653-659.

[39]GOMEZESPARZA C D, RAMIREZVALDESPINO C A, ESTRADAGUEL I, et al. Microstructural Study and Antibacterial Response of an AlCoCrCuFeMoNi High-entropy Alloy[J]. Microscopy and Microanalysis, 25(S2), 2646-2647.

[40]ZHU Jinming, ZHU Jieli, LIANG Jianlie. Microstructure and Mechanical Properties of Multi-principal Component AlCoCrFeNiCux Alloy[J]. Rare Metals, 2016, 35(5):385-389.

[41]LAI C H, LIN S J, YEH J W, et al. Effect of Substrate Bias on the Structure and Properties of Multi-element(AlCrTaTiZr)N Coatings[J]. Journal of Physics D: Applied Physics, 2006,39(21):4628-4633.

[42]LAI C H, TSAI M H, LIN S J, et al. Influence of Substrate Temperature on Structure and Mechanical, Properties of Multi-element (AlCrTaTiZr)N Coatings[J]. Surface & Coatings Technology, 2007,201(16/17):6993-6998.

[43]LAI C H, LIN S J, YEH J W, et al. Preparation and Characterization of AlCrTaTiZr Multi-element Nitride Coatings[J]. Surface and Coatings Technology, 2006,201(6):3275-3280.

[44]中科院宁波材料所. 非晶碳基抗磨蚀防护涂层材料研究取得进展[J]. 表面工程与再制造, 2018(6):61-62.

Ningbo Institute of Materials Technology & Engineering, CAS. Research Progress on Graphite-like Carbon Based Anti-wear Protective Coating Materials [J]. Surface Engineering & Remanufacturing, 2008(6):61-62.

[45]ZHENG Shujing, CAI Zhaobing, PU Jibin, et al. A Feasible Method for the Fabrication of VAlTiCrSi Amorphous High Entropy Alloy Film with Outstanding Anti-corrosion Property[J]. Applied Surface Science, 2019,483:870-874.

[46]CHEN Shengyu, CAI Zhaobing, LU Zhaoxia , et al. Tribo-corrosion Behavior of VAlTiCrCu High-entropy Alloy Film[J]. Materials Characterization, 2019,157:109887.

[47]HSIEH M H, TSAI M H, SHEN W J, et al. Structure and Properties of Two Al-Cr-Nb-Si-Ti High-entropy Nitride Coatings[J]. Surface and Coatings Technology, 2013,221:118-123.

[48]JOHANSSON K, RIEKEHR L, FRITZE S, et al. Multicomponent Hf-Nb-Ti-V-Zr Nitride Coatings by Reactive Magnetron Sputter Deposition[J]. Surface and Coatings Technology, 2018,349:529-539.

[49]邹林华, 黄伯云, 黄启忠, 等. 国外C/C复合材料摩擦学的研究现状[J]. 摩擦学学报, 2001, 21(2):157-160.

ZOU Linhua, HUANG Boiyun, HUANG Qizhong, et al.Current State of Tribological Investigation on Carbon-Carbon Composites at Abroad[J]. Tribology, 2001, 21(2):157-160.

[50]黄伯云, 肖鹏, 陈康华. 复合材料研究新进展(下)[J]. 金属世界, 2007(2):46-48.

HUANG Boiyun, XIAO Peng, CHEN Kanghua. New Progress of Composite Materials Research(Ⅱ)[J]. Metal World, 2007(2):46-48.

[51]王璐, 胡树兵, 单炜涛, 等. 激光熔覆NiCrMn-WC复合涂层的组织与耐磨性[J]. 中国有色金属学报, 2014, 24(1):145-151.

WANG Lu, HU Shubing, SHAN Weitao, et al.Microstructure and Wear Resistance of Laser Cladding NiCrMn-WC Composite Coatings[J]. The Chinese Journal of Nonferrous Metals, 2014, 24(1):145-151.

[52]张欣, 吴宜勇, 何世禹, 等. 抗原子氧有机/无机氧化硅复合涂层的研究[J]. 宇航材料工艺,2007（4）:23-27.

ZHANG Xin, WU Yiyong, HE Shiyu, et al.Structure and Properties of Organic /Inorganic Hybrid Silica Coatings[J]. Aerospace Materials and Technology, 2007(4):23-27.

[53]朱子新, 徐滨士, 张伟, 等. 高速电弧喷涂Fe-Al/WC复合涂层的组织和性能[J]. 材料工程,2002（5）:18-21.

ZHU Zixin, XU Binshi, ZHANG Wei, et al.Microstructure and Properties of Fe-Al/WC Coatings Prepared by High Velocity Arc Spraying[J]. Materials Engineering, 2002（5）:18-21.

[54]MARTINS R C, MOURA PAULO S, SEABRA J O. MOS2/Ti Low-friction Coating for Gears[J]. Tribology International, 2006, 39(12):1686-1697.

[55]LI Hao, ZHANG Guangan, WANG Liping. The Role of Tribo-pairs in Modifying the Tribological Behavior of the MoS2/Ti Composite Coating[J]. Journal of Physics D: Applied Physics, 2016,49(9): 095501.

[56]ZHANG Jingwen, WANG Yongxin, ZHOU Shengguo, et al. Tailoring Self-lubricating, Wear-resistance, Anticorrosion and Antifouling Properties of Ti/(Cu, MoS2)-DLC Coating in Marine Environment by Controlling the Content of Cu Dopant[J]. Tribology International, 2020，143：106029.

[57]TORGERSON T B, HARRIS M D, ALIDOKHT S A, et al. Room and Elevated Temperature Sliding Wear Behavior of Cold Sprayed Ni-WC Composite Coatings[J]. Surface and Coatings Technology, 2018,350:136-145.

[58]吴萍, 姜恩永, 周昌炽, 等. 激光熔覆Ni/WC复合涂层的组织和性能[J]. 中国激光, 2003, 30(4):357-360.

WU Ping, JIANG Enyong, ZHOU Changchi, et al.Microstructure and Properties of Ni/WC Composite Coating Prepared by Laser Cladding [J]. Chinese Journal of Lasers, 2003, 30(4):357-360.

[59]HARSHA S, DWIVEDI D K, AGARWAL A. Performance of Flame Sprayed Ni-WC Coating under Abrasive Wear Conditions[J]. Journal of Materials Engineering & Performance, 17(1):104-110.

[60]LIU Chengbao, QIU Shihui, DU Peng, et al. Ionic Liquid-graphene Oxide Hybrid Nanomaterial: Synthesis and Anticorrosive Applications[J]. Nanoscale, 2018, 10, 8115-8124.

[61]LIU Chengbao, DU Peng, ZHAO Haichao, et al. Synthesis of L-histidine-attached Graphene Nanomaterials and Their Application for Steel Protection[J]. ACS Applied Nano Materials, 2018,1:1385-1395.

[62]LIU Chengbao, ZHAO Haichao, HOU Peimin, et al. Efficient Graphene/Cyclodextrin-based Nanocontainer: Synthesis and Host-guest Inclusion for Self-healing Anticorrosion Application[J]. ACS Applied Materials & Interfaces 2018,10:36229-36239.

[63]蒲吉斌, 王立平, 薛群基. 多尺度强韧化碳基润滑薄膜的研究进展[J]. 中国表面工程, 2014, 27(6):4-27.

PU Jibin, WANG Liping, XUE Qunji.Progress in Strengthening and Toughening Carbon-based Films[J]. China Surface Engineering, 2014, 27(6):4-27.

[64]王云锋, 王立平, 张广安, 等. 碳化钛掺杂含氢类金刚石薄膜的力学和机械性能研究[C]∥2009年全国青年摩擦学学术会议论文集.长沙,2009：507.

WANG Yunfeng, WANG Liping, ZHANG Guangan, et al.Mechanical Properties of Titanium Carbide Doped Diamond-like Carbon Films[C]∥Proceedings of 2009 National Youth Tribology Conference. Changsha， 2009：507.

[65]郑越青, 王立平, 陈金明, 等. 中频非平衡磁控溅射沉积Ti-DLC膜摩擦磨损性能研究[J]. 润滑与密封2009,34(11):42-45.

ZHENG Yueqing, WANG Liping, CHEN Jinming, et al. Tribological Properties of Ti-DLC Films Deposited by Mid-frequency Dual-magnetron Sputtering[J]. Lubrication Engineering, 2009,34(11):42-45.

[66]崔明君, 任思明, 王永刚, 等. 石墨烯基防腐涂层研究进展[J]. 表面技术, 2019，48(6):46-55.

CUI Mingjun, REN Siming, WANG Yonggang, et al. Research Progress of the Graphene Coatings for Corrosion Protection[J]. Surface Technology, 2019，48(6):46-55.

[67]赵晓宇, 张广安, 王立平, 等. MoS2/Pb-Ti多层薄膜的结构和摩擦学性能[J]. 表面技术, 2018,47(10):108-117.

ZHAO Xiaoyu, ZHANG Guangan, WANG Liping, et al.Structure and Tribological Properties of MoS2/Pb-Ti Multilayer Films[J]. Surface Technology, 2018,47(10):108-117.

[68]CHEN Li, DU Yong, XIONG Xiang, et al. Improved Properties of Ti-Al-N Coating by Multilayer Structure[J]. International Journal of Refractory Metals and Hard Materials, 2011, 29(6):681-685.

[69]XU Yuxiang, CHEN Li, PEI Fei, et al. Effect of the Modulation Ratio on the Interface Structure of TiAlN/TiN and TiAlN/ZrN Multilayers: First-principles and Experimental Investigations[J]. Acta Materialia, 2017, 130:281-288.

[70]杨雨辉, 肖伟龙, 柴柯, 等. 碳含量和浸泡时间对碳钢热带自然海水腐蚀产物中细菌组成的影响[J]. 中国腐蚀与防护学报, 2011, 31(4):294-298.

YANG Yuhui, XIAO Weilong, CHAI Ke, et al. Composition of Bacteria in Corrosion Product of Carbon Steel with Different Carbon Content Immersed in Seawater for Different time[J]. Journal of Chinese Society for Corrosion and Protection, 2011, 31(4):294-298.

[71]牛艳, 林振龙, 林国基,等. Q235钢在海洋铁细菌作用下的腐蚀行为研究[J]. 海洋环境科学, 2014(5):739-744.

NIU Yan, LIN Zhenlong, LIN Guoji, et al. Research on Corrosion Behavior of Q235 Steel in Marine Iron-oxidizing Bacteria[J]. Marine Environmental Science, 2014(5):739-744.

[72]常雪婷. 海洋微生物附着腐蚀铁铝金属间化合物的机制研究[D].济南：山东大学, 2007.

CHANG Xueting. Study on Mechanisms of Microbiological Influence Corrosion for the Fe-Al Intermetallic Compounds[J]. Jinan: Shangdong University, 2007.

[73]吴进怡, 肖伟龙, 柴柯, 等. 热带海洋环境下海水中微生物对45钢腐蚀行为的单因素影响[J]. 金属学报, 2010,46(1):120-124.

WU Jinyi, XIAO Weilong, CHAI Ke, et al.The Single Effect of Microbe on the Corrosion Behaviors of 45 Steel in Seawater of Tropical Ocean Environment[J]. Acta Metallurgica Sinica, 2010,46(1):120-124.

[74]刘登良. 自修复(Self-healing)涂层材料——由观念创新到材料和产品创新[J]. 中国涂料, 2007(7):12-13.

LIU Dengliang.Self-healing Coating Materials-from Innovation of Concepts to Innovation of Materials and Products[J]. China Coatings, 2007(7):12-13.

[75]王巍, 王鑫, 刘晓杰, 等. 海洋环境中自修复涂层研究进展[J]. 装备环境工程, 2018, 15(10):98-106.

WANG Wei, WANG Xin, LIU Xiaojie, et al.Research Progress of Self-healing Coatings in Marine Environment [J]. Equipment Environmental Engineering, 2018, 15(10):98-106.

[76]ZHU Yebiao, DONG Minpeng, ZHAO Xiaoran, et al. Self-healing of TiSiN/Ag Coatings Induced by Ag[J]. Journal of the American Ceramic Society, 2019,102(12):7521-7532.

[77]ZHU Yebiao, DONG Minpeng, CHANG Keke, et al. Prolonged Anti-bacterial Action by Sluggish Release of Ag from TiSiN/Ag Multilayer Coating[J]. Journal of Alloys and Compounds, 2019,783:164-172.

[78]ZHANG Haijing, REN Siming, PU Jibin, et al. Barrier Mechanism of Multilayers Graphene Coated Copper Against Atomic Oxygen Irradiation[J]. Applied Surface Science, 2018, 444: 28-35.

[79]REN Siming, SHANG Kedong, CUI Mingjun, et al. Structural Design of MoS2-based Coatings toward High Humidity and Wide Temperature[J]. Journal of Materials Science, 2019, 54: 11889-11902.

[80]REN Siming, CUI Mingjun, PU Jibin, et al. Multilayer Regulation of Atomic Boron Nitride Films to Improve Oxidation and Corrosion Resistance of Cu[J]. ACS Applied Materials & Interfaces, 2017, 9: 27152-27165.

[81]鲁晓刚, 王卓, CUI Y W, 等. 计算热力学、计算动力学与材料设计[J]. 科学通报, 2013，58(35): 3656-3664.

LU Xiaogang, WANG Zhuo, CUI Y W, et al. Computational Thermodynamics, Computational Kinetics and Materials Design[J]. Chinese Science Bulletin (Chinese Version), 2013，58(35): 3656-3664.

[82]刘梓葵. 关于材料基因组的基本观点及展望[J]. 科学通报, 2013，58(35): 3618-3622.

LIU Zikui. Perspective on Materials Genome[J]. Chinese Science Bulletin (Chinese Version), 2013，58(35): 3618-3622.

[83]赵继成. 材料基因组计划中的高通量实验方法[J]. 科学通报, 2013，58(35): 3647-3655.

ZHAO Jicheng. High-throughput Experimental Tools for the Materials Genome Initiative[J]. Chinese Science Bulletin (Chinese Version), 2013，58(35): 3647-3655.

[84]GREN J. 材料基因组与相图计算[J]. 科学通报, 2013，58(35): 3633-3637.

gren J. The Materials Genome and CALPHAD [J]. Chinese Science Bulletin(Chinese Version), 2013，58(35): 3633-3637.

[85]陈龙庆. 相场模拟与材料基因组计划[J]. 科学通报, 2013，58(35): 3638-3641.

CHEN Longqing. Phase-field Method and Materials Genome Initiative (MGI)[J]. Chinese Science Bulletin(Chinese Version), 2013，58(35): 3638-3641.

[86]LI Qiang, ZHENG Shaoxian, PU Jibin, et al. Thermodynamics and Kinetics of an Oxygen Adatom on Pristine and Functionalized Graphene: Insight Gained into Their Anticorrosion Properties[J]. Physical Chemistry Chemical Physics, 2019, 21: 12121-12129.

[87]LI Qiang, ZHENG Shaoxian, PU Jibin, et al. Revealing the Failure Mechanism and Designing Protection Approach for MoS2 in Humid Environment by First-principles Investigation[J]. Applied Surface Science,2019,487:1121-1130.

[88]SPENCER P, HOLLECK H. Application of a Thermochemical Data-bank System to the Calculation of Metastable Phase Formation during PVD of Carbide, Nitride and Boride Coatings[J]. High Temperature Science, 1990, 27: 295-309.

[89]CHEN Qing, SUNDMAN B. Thermodynamic Assessment of the Ti-Al-N System[J]. Journal of Phase Equilibria, 1998,19(2):146-160.

[90]MAYRHOFER P, MUSIC D, SCHNEIDER J, et al. Influence of the Al Distribution on the Structure, Elastic Properties, and Phase Stability of Supersaturated Ti1-xAlxN[J]. Journal of Applied Physics, 2006, 100: 1-5.

[91]HOLEC D, ROVERE F, MAYRHOFER P H, et al. Pressure-dependent Stability of Cubic and Wurtzite Phases within the TiN-AlN and CrN-AlN Systems[J]. Scripta Materialia, 2010, 62: 349-352.

[92]LIU S D, CHANG K K, MRAZ S, et al. Modeling of Metastable Phase Formation for Sputtered Ti1-xAlxN Thin Films[J]. Acta Materialia, 2019, 165: 615-625.