AlNiZr非晶纳米晶复合涂层的腐蚀磨损行为研究

doi:10.3969/j.issn.1004-132X.2022.12.004

摘要/Abstract

摘要： 为提高海洋极端环境下钢结构材料的耐腐蚀磨损性能，采用高速电弧喷涂技术制备了一种AlNiZr非晶纳米晶复合涂层，并研究了该涂层在质量分数为3.5%的NaCl溶液中的腐蚀磨损行为。结果发现，AlNiZr涂层组织较为均匀，致密性较好，相结构由非晶、纳米晶及晶化相共同组成，涂层非晶体积分数约为64.93%，平均显微硬度值为363HV0.1，与45钢基体之间的平均结合强度约为30.8 MPa；在干摩擦条件下其平均摩擦因数约为0.125，磨损体积约为0.134 mm3，磨痕宽度约为882.4 μm，磨损失效机制以氧化磨损和脆性剥层磨损为主，并伴有轻微磨粒磨损；在腐蚀介质条件下，由于受到腐蚀介质的润滑减摩作用，导致涂层的平均摩擦因数、磨损体积、磨痕宽度均有明显减小，其平均摩擦因数约为0.058，磨损体积约为0.02216 mm3，磨痕宽度约为314 μm，腐蚀磨损失效机制主要表现为剥层磨损形式，同时磨损起主导作用、腐蚀次之。与纯铝涂层相比，AlNiZr涂层表现出优异的耐腐蚀磨损性能。

关键词: AlNiZr, 非晶, 涂层, 腐蚀磨损, 磨损失效

Abstract: In order to improve the corrosion and wear resistance of steel structure materials in marine extreme environments, a new kind of AlNiZr amorphous and nanocrystalline composite coating was prepared by high velocity arc spraying technology. The tribocorrosion behaviors of the AlNiZr coatings in 3.5 wt.% NaCl solution were studied. The results show that the arc-sprayed AlNiZr coatings have uniform microstructure and good density. The phase structure is composed of amorphous, nanocrystalline and crystalline phases. The volume fraction of amorphous phases in AlNiZr coatings is as about 64.93%, the average microhardness value is as 363 HV0.1, and the average bonding strength between the coatings and 45 steel is as about 30.8 MPa. Under the dry friction conditions, the arerage friction factor, wear volume and wear width of AlNiZr coatings are about 0.125, 0.134 mm3, and 882.4 μm, respectively. The wear failure mechanism of the coatings is mainly oxidative wear and brittle delamination wear, accompanied by slight abrasive wear. Under the corrosive conditions, the average friction factor, wear volume and wear width of the coatings decrease significantly due to the lubrication and antifriction of corrosive medium, which are about 0.058, 0.02216 mm3 and 314 μm, respectively. The corrosion wear failure mechanism of the coatings mainly exhibites in the form of delamination wear, and wear plays a leading role, followed by corrosion. Compared with the pure aluminum coatings, the AlNiZr coatings show excellent corrosion and wear resistance.

Key words: AlNiZr, amorphous, coating, corrosion wear, wear failure

中图分类号:

TG172.2

张志彬, 张舒研, , 鲁楠, 陈永雄, 梁秀兵. AlNiZr非晶纳米晶复合涂层的腐蚀磨损行为研究[J]. 中国机械工程, 2022, 33(12): 1435-1443.

ZHANG Zhibin, ZHANG Shuyan, LU Nan, CHEN Yongxiong, LIANG Xiubing. Study on Tribocorrosion Behaviors of AlNiZr Amorphous and Nanocrystalline Composite Coatings[J]. China Mechanical Engineering, 2022, 33(12): 1435-1443.

参考文献

［1］马秀敏, 郑萌, 徐玮辰, 等. 腐蚀成本及控制策略研究［J］. 海洋科学, 2021,45(2):161-168.
MA Xiumin, ZHENG Meng, XU Weichen, et al. Study of Corrosion Cost and Control Strategy［J］. Marine Sciences, 2021,45(2):161-168.
［2］LI X, ZHANG D, LIU Z, et al. Materials Science:Share Corrosion Data［J］. Nature, 2015,527(7579):441-442.
［3］ZHANG J, YU Z, ZHAO X, et al. The Interaction of Biofoulants and Calcareous Deposits on Corrosion Performance of Q235 in Seawater［J］. Materials, 2020,13(4):850.
［4］WANG Y, ZHANG J, ZHOU S, et al. Improvement in the Tribocorrosion Performance of CrCN Coating by Multilayered Design for Marine Protective Application［J］. Applied Surface Science, 2020,528:147061.
［5］CHENG J, GE Y, WANG B, et al. Microstructure and Tribocorrosion Behavior of Al2O3/Al Composite Coatings:Role of Al2O3 Addition［J］. Journal of Thermal Spray Technology, 2020,29(7):1741-1751.
［6］ZENG Q, XU Y. A Comparative Study on the Tribocorrosion Behaviors of AlFeCrNiMo High Entropy Alloy Coatings and 304 Stainless Steel［J］. Materials Today Communications, 2020,24:101261.
［7］CHEN J, CAI W. Effect of Scratching Frequency on the Tribocorrosion Resistance of Al-Mn Amorphous Thin Films［J］. Wear, 2019,426/427:1457-1465.
［8］AYYAGARI A, BARTHELEMY C, GWALANI B, et al. Reciprocating Sliding Wear Behavior of High Entropy Alloys in Dry and Marine Environments［J］. Materials Chemistry and Physics, 2018,210:162-169.
［9］LPEZ-ORTEGA A, ARANA J L, RODRGUEZ E, et al. Corrosion, Wear and Tribocorrosion Performance of a Thermally Sprayed Aluminum Coating Modified by Plasma Electrolytic Oxidation Technique for Offshore Submerged Components Protection［J］. Corrosion Science, 2018,143:258-280.
［10］LPEZ-ORTEGA A, BAYN R, ARANA J L. Evaluation of Protective Coatings for Offshore Applications. Corrosion and Tribocorrosion Behavior in Synthetic Seawater［J］. Surface and Coatings Technology, 2018,349:1083-1097.
［11］SHIH H C, HSU J W, SUN C N, et al. The Lifetime Assessment of Hot-dip 5% Al-Zn Coatings in Chloride Environments［J］. Surface and Coatings Technology, 2002,150(1):70-75.
［12］BOBZIN K, OETE M, LINKE T F, et al. Corrosion of Wire Arc Sprayed ZnMgAl［J］. Materials and Corrosion, 2015,66（6）:520-526.
［13］LIN J, WANG Z, CHENG J, et al. Evaluation of Cavitation Erosion Resistance of Arc-sprayed Fe-based Amorphous/Nanocrystalline Coatings in NaCl Solution［J］. Results in Physics, 2019,12:597-602.
［14］LEE H, SINGH J K, PARK J H. Pore Blocking Characteristics of Corrosion Products Formed on Aluminum Coating Produced by Arc Thermal Metal Spray Process in 3.5wt.% NaCl Solution［J］. Construction and Building Materials, 2016,113:905-916.
［15］LI P, HUANG X, KONG D. Corrosive Wear and Electrochemical Corrosion Performances of Arc Sprayed Al Coating in 3.5% NaCl Solution［J］. Anti-corrosion Methods and Materials, 2021,68(2):95-104.
［16］QIAO L, WU Y, DUAN J, et al. Corrosion Behavior of Arc-sprayed Pore-sealed Zn and Al Coatings in Seawater Containing Sulfate-reducing Bacteria (SRB)［J］. Journal of Thermal Spray Technology, 2021,30(6):1557-1565.
［17］CHEN H, KONG D. Comparison on Electrochemical Corrosion Performances of Arc and Laser Thermal Sprayed Al-Ti-Ni Coatings in Marine Environment［J］. Materials Chemistry and Physics, 2020,251:123200.
［18］GAO M H, ZHANG S D, YANG B J, et al. Prominent Inhibition Efficiency of Sodium Nitrate to Corrosion of Al-based Amorphous Alloy［J］. Applied Surface Science, 2020,530:147211.
［19］ZHANG L M, ZHANG S D, MA A L, et al. Influence of Cerium Content on the Corrosion Behavior of Al-Co-Ce Amorphous Alloys in 0.6 M NaCl Solution［J］. Journal of Materials Science & Technology, 2019,35(7):1378-1387.
［20］WU Y, ZHANG D. Electrochemical Corrosion Behaviors and Microhardness of Laser Thermal Sprayed Amorphous AlCrNi Coating on S275JR Steel［J］. Optics & Laser Technology, 2019,118:115-120.
［21］WEN J, SONG Z, CHEN X, et al. Fabrication of Porous Aluminum Coating by Cored Wire Arc Spray for Anchoring Antifouling Hydrogel Layer［J］. Journal of Thermal Spray Technology, 2022, 31:119-129.
［22］TAN C, ZHU H, KUANG T, et al. Laser Cladding Al-based Amorphous-nanocrystalline Composite Coatings on AZ80 Magnesium Alloy under Water Cooling Condition［J］. Journal of Alloys and Compounds, 2017,690:108-115.
［23］SHEN Y, PEREPEZKO J H. Al-based Amorphous Alloys:Glass-forming Ability, Crystallization Behavior and Effects of Minor Alloying Additions［J］. Journal of Alloys and Compounds, 2017,707:3-11.
［24］ZHANG Z, LIANG X, CHEN Y, et al. Preparation and Hardness Behavior of Al-based Amorphous/Nanocrystalline Composite Coatings on Mg Alloy Prepared by High Velocity Arc Spraying Process［J］. Materials Science Forum, 2011,694:256-260.
［25］ZHANG Z, LIANG X, XU B. Preparation of Al-based Amorphous/Nanocrystalline Composite Coating on Mg-based Alloys Precipitated by Arc Spraying Process［J］. Rare Metal Materials and Engineering, 2012,41(S1):439-442.
［26］梁秀兵, 范建文, 张志彬, 等. 铝基非晶纳米晶复合涂层显微组织与腐蚀性能研究［J］. 金属学报, 2018,54(8):1193-1203.
LIANG Xiubing, FAN Jianwen, ZHANG Zhibin, et al. Microstructure and Corrosion Properties of Aluminum Based Amorphous and Nanocrystalline Composite Coating［J］. Acta Metallurgica Sinica, 2018,54(8):1193-1203.
［27］梁秀兵, 张志彬, 陈永雄, 等. 铝基非晶纳米晶复合涂层研究［J］. 金属学报, 2012,48(3):289-297.
LIANG Xiubing, ZHANG Zhibin, CHEN Yong-xiong, et al. Study on Al-based Amorphous and Nanocrystalline Composite Coating［J］. Acta Metallurgica Sinica, 2012,48(3):289-297.
［28］梁秀兵, 周志丹, 张志彬, 等. 铝基非晶材料研究与再制造应用前景［J］. 材料导报, 2021,35(1):1003-1010.
LIANG Xiubing, ZHOU Zhidan, ZHANG Zhibin, et al. Al-based Amorphous Materials:Research and Remanufacturing Application Prospects［J］. Materials Reports, 2021,35(1):1003-1010.
［29］CHENG J B, WANG B L, LIU Q, et al. In-situ Synthesis of Novel Al-Fe-Si Metallic Glass Coating by Arc Spraying［J］. Journal of Alloys and Compounds, 2017,716:88-95.
［30］CHENG J B, FENG Y, YAN C, et al. Development and Characterization of Al-based Amorphous Coating［J］. JOM, 2020,72(2):745-753.
［31］VERDON C, KARIMI A, MARTIN J L. A Study of High Velocity Oxy-fuel Thermally Sprayed Tungsten Carbide based Coatings. Part 1:Microstructures［J］. Materials Science and Engineering:A, 1998,246(1/2):11-24.
［32］INOUE A, KIMURA H. High-strength Al-based Nanostructure Alloys［J］. Current Opinion in Solid State and Materials Science, 1997,2(3):305-310.
［33］TAKEUCHI A, INOUE A. Classification of Bluk Metallic Glasses by Atomic Size Difference, Heat of Mixing and Period of Constituent Elements and Its Application to Characterization of the Main Alloying Element［J］. Materials Transactions, 2005,46(12):2817-2829.
［34］ZHANG Z B, LIANG X B, CHEN Y X, et al. The Preparation and Corrosion Resistance of Al-Ni-Y-Co Amorphous and Nanocrystalline Composite Coating［J］. Materials and Corrosion, 2014,65(9):919-925.
［35］SUN W S, QUAN M X. Hardening Behavior of Amorphous Alloy Al90RE5Ni5 Dispersion by Nanoscale α-Al during Crystallization［J］. Materials Letters, 1996,27(3):101-105.
［36］HONG X, TAN Y, ZHOU C, et al. Microstructure and Tribological Properties of Zr-based Amorphous-nanocrystalline Coatings Deposited on the Surface of Titanium Alloys by Electrospark Deposition［J］. Applied Surface Science, 2015,356:1244-1251.

[1]	周嘉利, 程延海, 陈永雄, 梁秀兵, 白成杰, 杜望. 激光熔覆工艺参数对铁基双层涂层组织和残余应力的影响[J]. 中国机械工程, 2022, 33(12): 1418-1426，1434.
[2]	付宜风, 王虎鸣, 曹攀. 薄壁结构加强的纳米复合涂层深海高压吸声性能[J]. 中国机械工程, 2022, 33(12): 1444-1451.
[3]	董琳, 杨冠军, 张小锋, 刘梅军, 周克崧, 李璞, 朱昌发, 徐向毅, 刘坤. 抗水氧腐蚀致密环境障涂层研究进展[J]. 中国机械工程, 2022, 33(12): 1459-1467.
[4]	范庆波, 杨帆, 关晓艳, 李浩, 樊小强, 朱旻昊. TiVN涂层的耐磨性与切削性能的关联研究[J]. 中国机械工程, 2022, 33(12): 1493-1503.
[5]	韩冰源, 楚佳杰, 周克兵, 朱胜. 基于重熔技术的热喷涂涂层质量调控与性能优化现状研究[J]. 中国机械工程, 2022, 33(06): 727-739.
[6]	柯庆镝, 姜丰, 张鹏, 田常俊, 秦小州. 基于修复涂层力学性能影响规律的再制造毛坯表面污染物状态评估[J]. 中国机械工程, 2021, 32(19): 2340-2347,2356.
[7]	王涛, 朱磊, 唐杰, 王浩, 吴军. 双送粉激光熔覆CoCrAlSiY/YSZ梯度涂层微观组织及热振性能[J]. 中国机械工程, 2021, 32(15): 1854-1860.
[8]	李迎春1，2;程蓓1;邱明1，2;谷守旭1;范恒华1. 不同石墨烯添加量下MoS2基复合涂层的摩擦磨损及耐腐蚀性能[J]. 中国机械工程, 2020, 31(20): 2437-2444.
[9]	高健;赵自强;王文中. 基于热四极法的涂层刀具切削温度分布研究[J]. 中国机械工程, 2020, 31(19): 2316-2321.
[10]	张勇斌, 严广和, 李建原, 姜晨. 金刚石涂层微铣刀的铣削加工试验[J]. 中国机械工程, 2020, 31(15): 1772-1777.
[11]	常可可, 王立平, 薛群基. [学科发展]极端工况下机械表面界面损伤与防护研究进展[J]. 中国机械工程, 2020, 31(02): 206-220.
[12]	谢英星;王成勇;郑李娟;隋建波. 涂层刀具高速铣削淬硬钢的声发射信号特征[J]. 中国机械工程, 2019, 30(17): 2030-2039.
[13]	牛小强1;雷基林1;邓晰文1;文均2;温志高2. 活塞顶面热障涂层对活塞热负荷的影响[J]. 中国机械工程, 2018, 29(12): 1499-1506.
[14]	王敏. 铁基非晶合金涂层切削工艺参数优化和切削力预测[J]. 中国机械工程, 2017, 28(21): 2627-2631,2638.
[15]	李辉1;郑志镇1;吴晓1,2;李建军1. Zr55Cu30Al10Ni5块体非晶合金在超声振动场下的流变成形能力[J]. 中国机械工程, 2017, 28(20): 2514-2519.