中国机械工程 ›› 2025, Vol. 36 ›› Issue (10): 2472-2475.DOI: 10.3969/j.issn.1004-132X.2025.10.037

• 前沿快报 • 上一篇    

金刚石表面石墨烯瞬时共价键合改性

闫博, 陈妮(), 何宁, 佘嘉丰, 陈贤梓   

  1. 南京航空航天大学机电学院, 南京, 210016
  • 收稿日期:2025-09-03 出版日期:2025-10-25 发布日期:2025-11-05
  • 通讯作者: 陈妮
  • 作者简介:闫博,男,1997年生,博士研究生。主要研究方向为精密加工技术、金刚石刀具制备技术
    陈妮*(通信作者),女,1990年生,副教授、博士研究生导师。E-mail:ni.chen@nuaa.edu.cn
  • 基金资助:
    国家自然科学基金(52475464);国家自然科学基金(U2441264);江苏省自然科学基金优秀青年基金(BK20250173);南京航空航天大学博士学位论文创新与创优基金(BCXJ23-09)

Instantaneous Covalent Bonding Modification of Diamond Surfaces with Graphene

Bo YAN, Ni CHEN(), Ning HE, Jiafeng SHE, Xianzi CHEN   

  1. College of Mechanical and Electrical Engineering,Nanjing University of Aeronautics and Astronautics,Nanjing,210016
  • Received:2025-09-03 Online:2025-10-25 Published:2025-11-05
  • Contact: Ni CHEN

摘要:

面向航空航天、微机电系统、生物医学和核能等高新技术领域对金刚石工程表面的高使役性能需求,以及金刚石在高载/与黑色金属接触等条件下易发生石墨化和非晶化弱化转变、常规金刚石表面摩擦状态差等关键难题,提出金刚石表面石墨烯的“原位瞬时转化”新思想,发明激光诱导-飞轮机械解理方法,并在大气环境中稳定形成了一种独特的金刚石-纳米石墨-石墨烯共价结构。试验表明新结构协同了金刚石、石墨和石墨烯的优异性能,为金刚石工程应用瓶颈问题提供了新的解决途径,并有望为金刚石、金刚石涂层、石墨烯及全碳器件在机械、电子、航空航天等领域开辟新的应用前景。

关键词: 金刚石, 石墨烯, 共价结构, 性能协同, 刀具

Abstract:

The paper focused on the high-performance requirements for diamond engineering surfaces in high-tech fields such as aerospace, micro-electro-mechanical systems, biomedicine, and nuclear energy. It addressed key challenges including the susceptibility of diamond to graphitization and amorphization under high loads and contact with ferrous metals, as well as the poor frictional behavior of conventional diamond surfaces. A novel concept of “in-situ instantaneous transformation” of diamond surfaces into graphene was proposed, along with the development of a laser induced-flywheel mechanical cleavage method. This method successfully stabilized a unique diamond-nano-graphite-graphene covalent structure in ambient conditions. Experimental results demonstrate that this new structure synergizes the excellent properties of diamond, graphite, and graphene. It offers a novel approach to resolving engineering bottlenecks associated with diamond applications and holds promise for opening up new avenues for the use of diamond, diamond coatings, graphene, and all-carbon devices in mechanical, electronic, aerospace, and other fields.

Key words: diamond, graphene, covalent structure, performance synergy, cutting tool

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