碳化钨粉末表面涂层改性金刚石粉末的涂层工艺及机理

doi:10.3969/j.issn.1004-132X.2024.02.003

中国机械工程 ›› 2024, Vol. 35 ›› Issue (02): 208-214.DOI: 10.3969/j.issn.1004-132X.2024.02.003

碳化钨粉末表面涂层改性金刚石粉末的涂层工艺及机理

许左琳1;黄传真2;刘含莲1;刘盾1

1.山东大学机械工程学院，山东大学高效洁净机械制造教育部重点实验室，山东大学先进射流技术研究中心，济南，250061
2.燕山大学机械工程学院，秦皇岛，066004

出版日期:2024-02-25 发布日期:2024-03-22
通讯作者: 黄传真（通信作者），男，1966年生，教授，博士研究生导师。研究方向为高效精密加工技术、结构陶瓷材料、增材制造。发表论文400余篇。E-mail：huangchuanzhen@ysu.edu.cn。
作者简介:许左琳，男，1998年生，硕士研究生。研究方向为粉末表面涂层技术。E-mail：653484420@qq.com。
基金资助:
国家自然科学基金（52275464）

Coating Technology and Mechanism of Modified Diamond Powder by Surface Coating of WC Powders

XU Zuolin1;HUANG Chuanzhen2;LIU Huanlian1;LIU Dun1

1.School of Mechanical Engineering, Shandong University,Key Laboratory of High-efficiency
and Clean Mechanical Manufacture,Ministry of Education,Center for Advanced Jet Engineering
Technology(CaJET),Jinan,250061
2.School of Mechanical Engineering,Yanshan University,Qinhuangdao,Hebei,066004

Online:2024-02-25 Published:2024-03-22

摘要/Abstract

摘要： 粉末表面涂层技术能赋予粉末新的物理化学性质，电泳沉积技术能在改性碳化钨（WC）粉末表面涂层改性金刚石粉末。通过不同表征手段分析了金刚石的核壳结构及金刚石粉末与WC粉末间的包覆情况，研究了金刚石粉末含量对涂层效果的影响，比较了不同包覆工艺下粉末间的结合强度。结果表明，WC粉末质量与金刚石粉末质量的比为6∶1时，涂层效果最佳，改性后粉末间的强结合力来自COO-W、C-O-W等共价键形成的化学吸附与范德华力形成的物理吸附。

关键词: 粉末表面改性, 电泳沉积, 核壳结构, 结合强度

Abstract: The powder surface coating technology might endow the powder with new physical and chemical properties. By electrophoretic deposition technology, diamond powder was modified on the surface coating of WC powders. The core-shell structure of diamond and the coating between diamond powder and WC powder were analyzed by different characterization methods. The influences of diamond powder content on coating effectiveness were studied, and the bonding strength among powders was compared under different coating processes. The results show that when the mass ratio of WC powder to diamond powder is as 6∶1, the coating effectiveness is the best. The strong bonding force among the modified powders comes from the chemisorption formed by covalent bonds such as COO-W and C-O-W and the physical adsorption formed by van der Waals force.

Key words: , powder surface modification, electrophoretic deposition, core-shell structure, bond strength

中图分类号:

许左琳, 黄传真, 刘含莲, 刘盾. 碳化钨粉末表面涂层改性金刚石粉末的涂层工艺及机理[J]. 中国机械工程, 2024, 35(02): 208-214.

XU Zuolin, HUANG Chuanzhen, LIU Huanlian, LIU Dun. Coating Technology and Mechanism of Modified Diamond Powder by Surface Coating of WC Powders[J]. China Mechanical Engineering, 2024, 35(02): 208-214.

参考文献

［1］王铁钢, 张姣姣, 阎兵. 刀具涂层的研究进展及最新制备技术［J］. 真空科学与技术学报, 2017, 37(7):727-738.
WANG Tiegang, ZHANG Jiaojiao，YAN Bing. Latest Progress in Surface Modification of Cutting Tools with Coatings［J］. Chinese Journal of Vacuum Science and Technology, 2017, 37(7):727-738.
［2］李超国.微圆弧金刚石刀具质量的测量与评价技术［D］. 哈尔滨:哈尔滨工业大学,2021.
LI Chaoguo. Measurement and Evaluation Technology of Micro-arc Diamond Tool［D］. Harbin:Harbin Institute of Technology, 2021.
［3］刘毅. 微圆弧金刚石刀具超精密车削仿真与实验研究［D］. 绵阳:中国工程物理研究院, 2020.
LIU Yi. Simulation and Experimental Research on Ultra-Precision Turning of Micro-arc Diamond Tool［D］.Mianyang:China Academy of Engineering Physics, 2020.
［4］ZHANG B, DU Y. Experimental Study on High-speed Milling of SiCf/SiC Composites with PCD and CVD Diamond Tools［J］. Materials, 2021, 14(13):3470-3470.
［5］AL A, AL H A. A Review of Tribological Properties and Deposition Methods for Selected Hard Protective Coatings［J］. Tribology International, 2022, 176:107919.
［6］LI J S, HUANG C, LUO H, et al. Preparation of Diamond Coatings on Alumina by Hot Filament Chemical Vapor Deposition［J］. Materials Science Forum, 2015, 816:138-142.
［7］SITTINGER V, BARON S, HFER M, et al. Hot-filament CVD Diamond Coatings for Optical Applications［J］. Surface and Coatings Technology, 2023, 457:129287.
［8］LIN Q, CHEN S, SHEN B, et al. CVD Diamond Coated Drawing Dies:a Review［J］. Advanced Materials and Manufacturing Processes, 2021(4):381-408.
［9］吴雁, 李艳峰, 张而耕, 等. PVD涂层技术制备类金刚石薄膜及性能研究综述［J］. 表面技术, 2016, 45(8):115-123.
WU Yan, LI Yanfeng, ZHANG Ergeng, et al. PVD Coating Technology Preparation of Diamond-like Carbon Film and Its Performance［J］. Surface Technology, 2016, 45(8):115-123.
［10］范舒瑜, 匡同春, 林松盛, 等. WC-Co硬质合金/CVD金刚石涂层刀具研究现状［J］. 材料导报, 2023, 37(8):28-37.
FAN Shuyu, KUANG Tongchun, LIN Songsheng, et al. Research Progress on Cutting Tools Made from WC-Co Cemented Carbide Substrates and Coated with CVD Diamond［J］. Materials Reports, 2023, 37(8):28-37.
［11］WANG M, LIU H, WANG Y, et al. Stable Lubrication in Air and Vacuum of GO-Al3+ Coating Via Strong Chemical Bonding and Reactive Sites Passivation by Aluminum Ions［J］. Carbon, 2020, 160:247-254.
［12］杨旭, 程心雨, 刘荣正, 等. 流化床-化学气相沉积法制备金属涂层包覆燃料颗粒［J］. 清华大学学报(自然科学版), 2021, 61(4):361-366.
YANG Xu, CHENG Xinyu, LIU Rongzheng, et al. Preparation of Metal Coated Fuel Particles Using theFluidized Bed-chemical Vapor Deposition［J］. Journal of Tsinghua University(Natural Science), 2021, 61(4):361-366.
［13］杨鑫宇, 吴杰, 解帅, 等. 纳米级Pd/Fe@SiO2复合颗粒对2,4-DCP的还原脱氯研究［J］. 环境科学学报, 2019, 39(11):3794-3801.
YANG Xinyu, WU Jie, XIE Shuai, et al. Reductive Dechlorination of 2,4-DCP by Nano-sized Pd/Fe@SiO2 Nanocomposties［J］. Acta Scientiae Circumstantiae, 2019, 39(11):3794-3801.
［14］GAO Yuan, CHOI Eunmi, CUI Yinhua, et al. Selective Patterning on a Flexible Substrate Using Reduced Graphene Oxide-graphene and Electroless Deposited Self-aligned Silver Conduction Layers［J］. Applied Surface Science, 2020, 506:506144809.
［15］FU Z, LI X, REN Y, et al. Coating Y2O3 Nano-particles with ZrO2-additive via Precipitation Method for Colloidal Processing of Highly Transparent Y2O3 Ceramics.［J］. Journal of the European Ceramic Society, 2019(15):4996-5004.
［16］SONG Z J, LIU S K. Optimized Preparation of MgO-ZrO Nanocomposite Powders by Assisted Sol-gel Method［J］. Journal of Physics:Conference Series, 2022(1):2390-2401.
［17］RUCKENSTEIN E, BERIM G O, NARSIMHAN G. A Novel Approach to the Theory of Homogeneous and Heterogeneous Nucleation［J］. Advances in Colloid and Interface Science, 2015, 215:13-27.
［18］XINNA Z, KAI M, TIFENG J, et al. Fabrication of Hierarchical Layer-by-layer Assembled Diamond-based Core-shell Nanocomposites as Highly Efficient Dye Absorbents for Wastewater Treatment.［J］. Scientific Reports, 2017, 7(1):44076.
［19］LIU X A, ZHAO Q A, VELDHUIS S A, et al. Cholic Acid is a Versatile Coating-forming Dispersant for Electrophoretic Deposition of Diamond, Graphene, Carbon Dots and Polytetrafluoroethylene.［J］. Surface & Coatings Technology, 2020, 384:125304.
［20］师琦, 吴素芳. 沉淀法SiO2包覆纳米CaCO3吸附剂性能［J］. 化工学报, 2009(2):507-513.
SHI Qi, WU Sufang. Properties of SiO2 Coated Nano SiO2/CaCO3 Sorbents by Precipitation Method［J］. CIESC Journal, 2009(2):507-513.
［21］WU Guangyong, XU Chonghai, XIAO Guangchun, et al. Self-lubricating Ceramic Cutting Tool Material with the Addition of Nickel Coated CaF2 Solid Lubricant Powders［J］. International Journal of Refractory Metals and Hard Materials, 2016, 56:51-58.
［22］万志坚, 黄传真. 硬质合金粉末表面电泳沉积制备金刚石涂层［J］. 金刚石与磨料磨具工程, 2019, 39(1):80-83.
WAN Zhijian, HUANG Chuanzhen. Preparing Diamond Coating on Cemented Carbide Powder by Electrophoretic Deposition［J］. Diamond and Abrasives Engineering, 2019, 39(1):80-83.
［23］FENG Yalin, CHEN Xingyun, MA Yongcun, et al. Fabrication of an Orderly Layered Nanostructure Coating via Cathodic EPD of Silanized GO Nanosheet for Anti-corrosion Protection［J］. Colloids & Surfaces a:Phys. Eng. Asp., 2021, 610:125754.
［24］CHEN X, FENG Y, MA Y, et al. A Facile Cathodic Electrophoretic Deposition(EPD) of GO Nanosheet with an Orderly Layered Nanostructure for Development of Long-term Durability Anticorrosive Coating［J］. Progress in Organic Coatings, 2021, 151:106034.
［25］JIANG J J, YAO X M, XU C M, et al. Influence of Electrochemical Oxidation of Carbon Fiber on the Mechanical Properties of Carbon Fiber/graphene Oxide/Epoxy Composites［J］. Composites Part a:Applied Science and Manufacturing, 2017, 95:248-256.
［26］HUANG S Y, WU G P, CHEN C M, et al. Electrophoretic Deposition and Termal Annealing of a Graphene Oxide Thin Film on Carbon Fiber Surfaces［J］. Carbon, 2013, 52:613-616.
［27］万志坚. 硬质合金粉末表面涂层金刚石的新型刀具材料研制［D］. 济南:山东大学, 2019.
WAN Zhijian. Development of a New Tool Materials with Cemented Carbide Powder Coated by Diamond［D］. Jinan:Shandong University, 2019.
［28］LIN Y M, WU K H, YU L H, et al. Efficient and Highly Selective Solvent-free Oxidation of Primary Alcohols to Aldehydes Using Bucky Nanodiamond［J］. Chemsuschem, 2017, 10(17):1497-3505.
［29］陈元春, 黄传真, 艾兴, 等. 粉末表面涂层陶瓷的硬质合金刀具材料［J］. 无机材料学报, 2000(5):873-878.
CHEN Yuanchun, HUANG Chuanzhen, AI Xing, et al. Advanced Cutting Tool Material by Hot-pressing Ceramic Coated Carbid Powders［J］. Journal of Inorganic Materials, 2000(5):873-878.
［30］李莉萍, 吴道义, 战奕凯, 等. 电泳沉积碳纳米管和氧化石墨烯修饰碳纤维表面的研究进展［J］. 纺织学报, 2020, 41(6):168-173.
LI Liping, WU Daoyi, ZHAN Yikai, et al. Review on Carbon Fiber Surface Modification Using Electrophoretic Deposition of Carbon Nanotubes and Graphene Oxide［J］. Journal of Textile Science, 2020, 41(6):168-173.

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碳化钨粉末表面涂层改性金刚石粉末的涂层工艺及机理

Coating Technology and Mechanism of Modified Diamond Powder by Surface Coating of WC Powders

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